Product ID:CARBON DIOXIDE, REFRIGERATED LIQUID
MSDS Date:01/01/1988
FSC:4210
NIIN:00-203-0217
MSDS Number: BJRCD

Emergency Phone: 312-771-2990

Info Phone: 312-771-2990

Cage: 84168

Telephone: (708) 847-272-7500; 847-272-7500

Cage: 99539

NO INGREDIENT FOR THIS FORMULATION_INGREDIENT

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPOR IN CONCENTRATIONS
OF 3-5% VOLUME IN AIR CAUSES INCREASED RESPIRATION AND HEADACHE;
8-15% CONCENTRATIONS CAUSE HEADACHE, NAUSEA, AND VOMITING, WHICH
MAY LEAD TO UNCONSCIOUSNESS IF V ICTIM IS NOT MOVED TO OPEN AIR OR
GIVENOXYGEN; HIGHER CONCENTRATIONS CAUSE RAPID CIRCULATORY (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INSUFFICIENCY LEADING TO COMA AND
DEATH. PHYSICAL CONTACT WITH LIQUIFIED OR SOLID CARBON DIOXIDE CAN
CAUSE FROSTBITE OR FREEZE BURNS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: CONSCIOUS PERSONS SHOULD BE ASSISTED TO AN
UNCOMTAMINATED AREA AND INHALE FRESH AIR. QUICK REMOVAL FROM
CONTAMD AREA IS MOST IMPORTANT. UNCONSCIOUS PERSONS SHOULD BE MOVED
TO AN UNCONTAMD AREA, GIVEN MOUTH TO MOUTH RESUSCITATION
ANDSUPPLEMENTAL OXYGEN. FURTHER TREATMENT SHOULD BE SYMPTOMATIC &
SUPPORTIVE. EYE: IMMED FLUSH WITH TEPID WATER IN LRG QTYS FOR AT
LEAST 15 MIN (SEE SUPP DATA)

Flash Point:NONE
Unusual Fire/Explosion Hazard:NONE. CO*2 IS NON-FLAM INERT GAS.
HOWEVER, EXPOS TO FIRE/SEV OVERHEATING CAN CAUSE CARBON DIOXIDE CYL
TO BURST (CONT CYL MFR FOR DETAILS). (SEE SUPP DATA)

Spill Release Procedures:EVAC ALL PERSONNEL FROM AREA. USING APPROP
PROT EQUIP, PROVIDE VENT TO AREA AND AVOID CONT W/SOLID OR LIQ AND
EXCESSIVE INHAL OF VAP. VALVE OFF CARBON DIOXIDE SUPPLY FROM
LEAKING/BROKEN COMPONENTS. DO NOT RE-ENTER UNTIL TLV REQUIREMENTS
ARE MET.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROVIDE GEN & LOC EXHAUST VENT TO MEET
TLV REQUIREMENTS. PROVIDE APPRVD NIOSH/MSHA SUPPLIED AIR/SCBA WHEN
EXPOS ARE ABOVE TLV. (SEE OTHER PREC)
Other Precautions:HNDLG STOR PREC: DO NOT INSTALL STORAGE VESSELS IN
SUB SURFACE OR CLOSED AREAS, OR NEAR EXCESSIVE HEAT OR FLAME.

Respiratory Protection:NIOSH/MSHA APPROVD POSITIVE PRESS AIR LINE WITH
FULL FACEPIECE AND ESCAPE AIR SUPPLY OR SCBA SHOULD BE AVAIL FOR
EMERGENCY USE.
Ventilation:SUFFICIENT TO PREVENT ACCUMULATION ABOVE TLV. LOCAL EXHAUST
SHOULD BE LOCATED NEAR THE FLOOR.
Protective Gloves:INSULATED & COLD RESISTANT.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS FREQUENTLY AND THOROUGHLY DURING
CONTACT WITH MATERIAL AND AT END OF WORKDAY .
Supplemental Safety and Health
VP: 291.1 PSIG @ 0F. EXPLO HAZ: BULK LIQ STORAGE CNTNRS ARE ALSO
PRESSURIZED. CONSULT W/MFR/SUPPLIER BEFORE ATTEMPTING SERVICE,
REPAIR, REMOVAL/ALTERATION. FIRST AID PROC: OR W/A STERILE SALINE
SOLN. GET MD. SKIN: FOR DERMAL CONT/FROSTBITE, FLUSH AFFECTED AREA
W/LUKEWARM WATER. DO NOT USE HOT WATER. (SEE INGRED 2)

Boiling Pt:B.P. Text:-109F,-79C
Melt/Freeze Pt:M.P/F.P Text:-109F,-79C
Vapor Pres:SUPP DATA
Spec Gravity:1.65 @ 70F
Solubility in Water:1 TO 1 @ 60F & 1 ATM
Appearance and Odor:COLORLESS, ODORLESS GAS; MILKY WHITE SOLID; WATER
WHITE LIQUID.

Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE

Waste Disposal Methods:CONTAMINATED AREA SHOULD BE VENTILATED
THOROUGHLY. SOLID CARBON DIOXIDE SHOULD BE REMOVED OUT OF DOORS AND
ALLOWED TO SUBLINATE. DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.